News Reader.info

ABSTRACT Spin-based sensors have attracted considerable attention owing to their high sensitivities. Herein, we developed a metallofullerene-based nano spin sensor to probe gas adsorption

within porous organic frameworks. For this, spin-active metallofullerene, Sc3C2@C80, was selected and embedded into a nanopore of a pyrene-based covalent organic framework (Py-COF). Electron

paramagnetic resonance (EPR) spectroscopy recorded the EPR signals of Sc3C2@C80 within Py-COF after adsorbing N2, CO, CH4, CO2, C3H6, and C3H8. Results indicated that the regularly changing

EPR signals of embedded Sc3C2@C80 were associated with the gas adsorption performance of Py-COF. In contrast to traditional adsorption isotherm measurements, this implantable nano spin

sensor could probe gas adsorption and desorption with in situ, real-time monitoring. The proposed nano spin sensor was also employed to probe the gas adsorption performance of a

metal–organic framework (MOF-177), demonstrating its versatility. The nano spin sensor is thus applicable for quantum sensing and precision measurements. SIMILAR CONTENT BEING VIEWED BY

OTHERS MAGNETIC SUSTENTATION AS AN ADSORPTION CHARACTERIZATION TECHNIQUE FOR PARAMAGNETIC METAL-ORGANIC FRAMEWORKS Article Open access 05 January 2023 DEVELOPMENT OF A HIGH PERFORMANCE

ETHYLENE GLYCOL GAS SENSOR USING COBALT DOPED POROUS ZNFE2O4 NANOSTRUCTURES Article Open access 15 May 2025 IDENTIFICATION OF CO2 ADSORPTION SITES ON MGO NANOSHEETS BY SOLID-STATE NUCLEAR

MAGNETIC RESONANCE SPECTROSCOPY Article Open access 04 February 2022 INTRODUCTION Recently, the use of electron spins for advanced science and technology has been actively pursued owing to

their genuine quantum characteristics1,2,3,4. Consequently, spin-based sensors have gained significant attention owing to their high sensitivities and broad applications in probing physical

and chemical parameters, such as electrical5 or magnetic fields3, molecule6 or protein dynamics7, and nuclei8,9 or other particles. Along with this spin-based sensing research, quantum

sensing has also emerged, causing a significant change in the paradigms of metrology. For example, spin-bearing diamonds with nitrogen-vacancy centers have been extensively studied for

quantum sensing10,11,12,13. Moreover, several other spin systems could also potentially perform unique functions, such as quantum probing, which must be explored. Among these, molecular

spins exhibit unique quantum properties, and certain proposals based on molecular spins for quantum computation and information storage have attracted considerable attention from physicists

and chemists14,15,16. In particular, molecular spin systems feature numerous advantages, including the molecular-level chemical engineering of their spins. Moreover, molecular spins have

independent nanoscale units that can realize in situ monitoring complex systems. Therefore, molecular spins demonstrate potential for quantum sensing applications. Notably, paramagnetic

endohedral metallofullerenes are nanoscale ball-like molecules with sensitive electron spins17,18,19,20. Owing to the presence of a fullerene cage, the endohedral electron spin presents high

chemical stability. Moreover, the most significant advantages of such metallofullerene molecules are their susceptible electron spins, which can be potentially employed in quantum sensing

applications. Accordingly, recent studies have explored the susceptible electron spins of metallofullerene molecules for sensing local magnetic fields, nanospace, molecule orientations, and

molecule motions20,21,22,23,24. To promote these applications, it is, however, essential to explore appropriate sensing systems. Porous organic frameworks are emerging crystalline porous

materials with broad applications in gas adsorption and separation25,26,27,28, gas storage29,30, sensing31,32,33,34,35,36, and catalysis37,38,39. Notably, covalent organic frameworks (COFs)

and metal–organic frameworks (MOFs) have been investigated for extensive applications. For example, COFs have attracted significant interest owing to their wide surface areas and

hierarchical nanopores, which are capable of encapsulating several guest species and causing chemical and physical changes. To reveal the adsorption mechanism and promote future

applications, understanding and monitoring the nanopores within COFs, specifically detecting these nanopores in situ, are crucial steps. However, effective methods for such measurements are

currently lacking. Notably, the aromatic fullerene shell of metallofullerenes endows them with lipophilicity, making them COF-nanopore-accessible. Therefore, paramagnetic endohedral

metallofullerenes with sensitive electron spins can potentially sense COF nanopores in situ. For a proof-of-concept study, we used a representative paramagnetic metallofullerene, Sc3C2@C80,

as an embedded spin probe to sense gas adsorption within a pyrene-based COF (Py-COF). Note that Sc3C2@C80 has a highly stable electron spin protected by a carbon cage, and this stability

forms the basis of its application. Moreover, Sc3C2@C80 has a highly sensitive electron spin, as reported in our previous studies18,40,41. These features make Sc3C2@C80 suitable for gas

adsorption detection within porous materials. Py-COF, prepared using self-condensing building blocks with formyl and amino groups, is a recently emerging porous organic framework material

with unique adsorption properties42. Its theoretical pore size is 1.38 nm; thus, one metallofullerene Sc3C2@C80 unit (approximately 0.8 nm in size) can enter one nanopore of Py-COF.

Therefore, the molecular spin of Sc3C2@C80 can effectively sense a nanopore of Py-COF in situ. In this study, the molecular spin of Sc3C2@C80 was employed to probe the gas adsorption

performance of Py-COF for N2, CO, CO2, CH4, C3H6, and C3H8 gases by recording the electron paramagnetic resonance (EPR) signals of the embedded Sc3C2@C80. The EPR intensities of the embedded

Sc3C2@C80 were observed to change when Py-COF adsorbed different gases. Therefore, the adsorption isotherms of Py-COF for different gases were recorded to comparatively illustrate the gas

adsorption performance. Additionally, an in situ and real-time gas sensing process of Py-COF based on embedded Sc3C2@C80 was designed, further demonstrating the application potential of this

nano spin sensor. Moreover, the mechanism and evaluation methodology of this spin sensor were studied by analyzing the EPR signal intensity and linewidth. Finally, Sc3C2@C80 was employed to

probe the gas adsorption performance of an MOF (MOF-177), illustrating the versatility of this nano spin sensor. RESULTS EPR STUDIES OF METALLOFULLERENE ENTRAPPED INSIDE PY-COF The basic

concept underlying the metallofullerene-based nano spin sensor used for probing the gas adsorption performance of Py-COF is presented in Fig. 1a. Generally, when gas molecules are adsorbed

onto COF or MOF materials, these molecules adhere to the pore frameworks and form gas layers on the frameworks43,44,45. These gas layers then restrict the motion of embedded Sc3C2@C80,

intensify spin–lattice interactions, and consequently weaken EPR signals. In this case, more gas molecules would enhance the thickness and viscosity of these gas layers and further weaken

the EPR signals of embedded Sc3C2@C80. For this testing platform, a nano spin sensor involving Sc3C2@C80 embedded in a Py-COF channel can sense gas adsorption through spin–lattice

interactions, which influence the EPR signal intensity and linewidth. Typically, Py-COF is synthesized using bifunctional monomeric 1,6-bis(4-formylphenyl)−3,8-bis(4-aminophenyl)pyrene, with

two formyl and two amino groups, through intermolecular self-condensation, forming a 2D pyrene-based imine COF42. Py-COF demonstrates good thermal stability, as revealed by

thermogravimetric analysis (Supplementary Fig. 1). In our study, Sc3C2@C80 was synthesized using the Kräschmer−Huffman arc-discharge method46, and Supplementary Fig. 2 shows the preparation

and characterization details. As presented in Fig. 1b, Sc3C2@C80 has an unpaired electron localized in the Sc3C2 cluster. A theoretically computed unit structure of Sc3C2@C80⊂Py-COF is shown

in Fig. 1c. The theoretical pore size of Py-COF is 1.38 nm; thus, a pore of Py-COF can effectively accommodate a metallofullerene Sc3C2@C80 unit (approximately 0.8 nm in size) through

host–guest interactions, including van der Waals forces and certain π–π interactions. The predicted position of Sc3C2@C80 within Py-COF pores indicates that the molecular spin of Sc3C2@C80

can sense the environment of a Py-COF nanopore in situ. In addition, the encapsulation of Sc3C2@C80 inside the channel of a Py-COF would not substantially prevent gases from infiltrating,

and ample space may be available for gas adsorption, as observed from Fig. 1c. Sc3C2@C80 was entrapped in Py-COF using the adsorption method in a toluene solution, yielding a complex of

Sc3C2@C80⊂Py-COF, as shown in Fig. 1d and Supplementary Fig. 3a. After the adsorption of Sc3C2@C80, the color of Py-COF changed from light yellow to brown, and the obtained complex was

sufficiently washed using toluene to remove Sc3C2@C80 physically adhered on the Py-COF surface. Moreover, the mass fraction of Sc3C2@C80 in Py-COF was calculated to be 1.5% (Supplementary

Fig. 3b), and the analysis process is presented in Supplementary Note 1. Next, PXRD experiments were performed to characterize the crystallinity of Py-COF and Sc3C2@C80⊂Py-COF, as shown in

Fig. 1d. A comparison between their PXRD patterns indicated that Sc3C2@C80 did not disrupt the crystal structure of Py-COF. The detection of the Sc 2_p_ peak in Sc3C2@C80⊂Py-COF via X-ray

photoelectron spectroscopy (XPS) indicated that Sc3C2@C80 molecules were trapped inside the channels of Py-COF, as shown in Supplementary Fig. 4. Scanning electron microscopy (SEM) images of

Py-COF and Sc3C2@C80⊂Py-COF revealed that the composite material morphology and size did not change after preparation (Supplementary Fig. 5). The transmission electron microscopy (TEM)

element mapping images and energy dispersive spectroscopy results revealed that Sc3C2@C80 was uniformly distributed inside Py-COF (Supplementary Fig. 6). The EPR spectra of Sc3C2@C80⊂Py-COF

under vacuum and after adsorbing the gases are shown in Fig. 1f. The apparent distinct EPR splitting peaks indicate successful embedment and dispersion of Sc3C2@C80 molecules, as simple

physical dispersion could lead to the aggregation of Sc3C2@C80, which would present a broad single EPR peak. In addition, the EPR spectrum of Sc3C2@C80 in a CS2 solution presents 22

splitting peaks owing to the couplings between spin and three equivalent Sc nuclei, as shown in Supplementary Fig. 13. However, the EPR spectrum of Sc3C2@C80⊂Py-COF under vacuum presented

broadened EPR signals owing to the strong host–guest interaction between Sc3C2@C80 and the pores of Py-COF, which can intensify spin–lattice interactions and change the EPR signals.

Subsequently, Sc3C2@C80 was employed to probe the gas adsorption performance of Py-COF for N2, CO, CO2, CH4, C3H6, and C3H8 by recording the EPR signals. Figure 1e presents a sketch of the

experimental setup. The EPR spectra of Sc3C2@C80⊂Py-COF varied under different conditions. Briefly, after adsorbing the above gases, the EPR signal intensity of Sc3C2@C80⊂Py-COF decreased

compared to that under vacuum conditions, and the EPR signals of Sc3C2@C80⊂Py-COF changed. To further analyze the EPR signals under different conditions, integral EPR spectra were obtained,

as shown in Fig. 1g. The intensities of the EPR signals under vacuum conditions were the strongest, and the intensities under gas adsorption conditions gradually decreased in the following

order: N2, CO, CH4, CO2, C3H8, and C3H6. In addition, the difference values between the integrated EPR signal intensity (integrated EPR signal area) of Sc3C2@C80⊂Py-COF before and after gas

adsorption are plotted in Fig. 1h, which demonstrates that the difference values of the integrated EPR signal intensity gradually increased in the following order: N2, CO, CH4, CO2, C3H8,

and C3H6. As discussed above, when gas molecules adhere to porous frameworks, gas layers are formed on them. These gas layers restrict the motion of embedded Sc3C2@C80 and intensify

spin–lattice interactions. In this scenario, more gas molecules would enhance the viscosity of these gas layers and influence the rotational relaxation time of Sc3C2@C80 molecules. The

relationship between the viscosity _η_ and rotational correlation time _τ__c_ in the spin system can be expressed as47 $${\tau }_{c}=\frac{4\pi {r}^{3}\eta }{3{kT}}$$ (1) where _r_ is the

dynamic radius of a spin molecule. The spin–lattice relaxation time (T1) is expressed as follows48: $$\frac{1}{{T}_{1}}=\frac{{2\pi g\beta

}_{e}}{h}\left({B}_{x}^{2}+{B}_{y}^{2}\right)\frac{{\tau }_{c}}{1+{\tau }_{c}^{2}{\omega }_{s}^{2}}$$ (2) where \({B}_{x}^{2}+{B}_{y}^{2}\) denote the square amplitudes of fluctuating fields

along the x- and y-directions. According to Eqs. (1) and (2), a larger viscosity could result in a smaller T1. Furthermore, the double-integrated intensity (DIN) can be expressed by the

Arrhenius equation49: $${{{{{\rm{DIN}}}}}}\left(T\right)={I}_{0}\exp \left(\frac{{E}_{a}}{{kT}}\right)$$ (3) where _I_0 is a fitting parameter, and _E__a_ is the activation energy required

for dissociation of the paramagnetic spin cluster. Combining T1 with Eq. (3) 1/T1 ∝ exp(-_E__a_/_kT_)50 reveals that the integrated EPR intensity would decrease with a decrease in T1.

Therefore, a corresponding relationship exists between gas adsorption and EPR signals. GAS ADSORPTION ANALYSIS OF PY-COF Next, the adsorption capacities of Py-COF for the aforementioned

gases were then measured based on adsorption isotherms, as shown in Fig. 2a and Supplementary Fig. 7. Py-COF demonstrated increasing adsorption capacity at 1 bar for the above gases in the

following order: N2, CO, CH4, CO2, C3H8, and C3H6. Notably, this order of adsorption capacity was identical to that of the changed EPR signals of Sc3C2@C80⊂Py-COF before and after adsorbing

different gases at 1 bar, as shown in Fig. 2b. Thus, in addition to the increase in the adsorption amount of Py-COF, the difference between the integrated EPR signal intensity for

Sc3C2@C80⊂Py-COF before and after adsorbing gas increased. This unique relationship indicates that embedded Sc3C2@C80 can be used as a molecular nanosensor to probe the gas adsorption

performance of Py-COF and other porous organic frameworks. In addition, differences between the change trends obtained based on the adsorption isotherm and EPR measurements were observed.

This was because the commonly used adsorption isotherm test analyzes the gas adsorption of all pores within Py-COF, whereas EPR measurements only reflect the gas adsorption near Sc3C2@C80 in

a nanoscale channel of Py-COF. As shown in Supplementary Fig. 10, Py-COF displays a combined type I dominant isotherm with a sharp uptake in the low relative pressure region51 (P/P0 < 

0.1), a characteristic of microporous materials. Although the pore size of Py-COF demonstrated a theoretical distribution centered at 1.38 nm, some sub-nanoscale cracks could be observed.

These cracks could result in a non-equivalent relationship between the amounts obtained from the adsorption isotherm and EPR measurements. Therefore, the N2 sorption analysis revealed the

average porosity of Py-COF. However, EPR measurements with a spin sensor involving Sc3C2@C80 entrapped in Py-COF could be used to probe the gas adsorption performance and adsorption and

desorption processes with in situ and real-time monitoring. In addition, we performed contrast adsorption isotherm experiments on C3H6 and C3H8 gases for Py-COF and C60⊂Py-COF (mass

fraction: 9.8%), indicating that the adsorption capacity of Py-COF did not change after fullerene encapsulation (Supplementary Fig. 8). Thus, a small amount of fullerene inside Py-COF would

not prevent the gas from infiltrating. PROBING GAS ADSORPTION OF COFS WITH A NANO SPIN SENSOR Generally, sensitivity is an essential parameter for a probe. For the proposed nano spin sensor,

detecting gas adsorption at low pressures is a significant indicator of sensitivity. To investigate the sensitivity of this spin probe, we recorded EPR signals at 0.2 bar and 0.6 bar for

N2, CO, CH4, and CO2, as shown in Fig. 3a, b. After adsorption of N2, CO, CH4, and CO2 at 0.2 bar and 0.6 bar, the EPR signal intensity of Sc3C2@C80⊂Py-COF decreased compared to that under

vacuum conditions. Moreover, integral EPR spectra were obtained, and the intensities under gas adsorption conditions of 0.2 bar and 0.6 bar decreased in the following order: N2, CO, CH4, and

CO2. The trends of the changed difference values for the integrated EPR signal areas of Sc3C2@C80⊂Py-COF before and after adsorbing different gases at 0.2 bar and 0.6 bar are shown in Fig.

3c, and the difference values for the integrated EPR signal areas appear to be significant under low pressures. In addition, the adsorption capacity of Py-COF for the gases (N2, CO, CH4, and

CO2) could still be well distinguished at 0.2 bar and 0.6 bar (Supplementary Fig. 11). Moreover, the EPR signals after gas adsorption under lower pressures were recorded, as shown in

Supplementary Fig. 9. These EPR tests were performed under the following conditions: 0.12 bar CO2, 0.03 bar C3H8, and 0.04 bar C3H6 see in Supplementary Note 3. Sc3C2@C80⊂Py-COF was able to

sense gas adsorption at extremely low pressures, revealing the high sensitivity of this molecular spin probe based on metallofullerene Sc3C2@C80. To date, relevant EPR methods to probe gas

adsorption have seldom been reported; yet there are few reports on the EPR properties of TEMPO radicals within MOF materials. For example, for a TEMPO radical and ZIF-8 complex, the

adsorption of different gases at atmospheric pressure was found to change the rotational correlation time of the TEMPO radical52. In addition, the TEMPO radical and ZIF-8 complex were

involved in investigations on high-pressure induced amorphization53. We consider this molecular spin probe based on metallofullerene Sc3C2@C80 for the gas adsorption measurement of porous

organic frameworks to be closer to sensing application. As mentioned, EPR measurements using a nano spin sensor involving Sc3C2@C80 entrapped in a Py-COF could be used to probe the

adsorption and desorption processes. To illustrate this concept, we designed a group of EPR experiments in which C3H6 gas was selected as a detection object. As shown in Fig. 4a, four states

of Sc3C2@C80⊂Py-COF were selected to record the EPR spectra, with 20 repeated measurements performed for each state to avoid instrumental errors. Sc3C2@C80⊂Py-COF under vacuum, State I,

presented high-intensity integrated EPR signals (Fig. 4b and Supplementary Fig. 12). However, after absorbing N2, State II, the integrated EPR signals of Sc3C2@C80⊂Py-COF decreased slightly

in intensity. Notably, after absorbing C3H6, State III, the integrated EPR signals of Sc3C2@C80⊂Py-COF decreased significantly in intensity. Finally, after another vacuum treatment, State

IV, Sc3C2@C80⊂Py-COF could recover its high-intensity EPR signals. These results demonstrate that the nano spin sensor involving Sc3C2@C80 entrapped in a Py-COF could detect the existence or

leakage of C3H6 gas, an essential chemical material. In addition, we compared the EPR signals of different gases at the same adsorption capacity and discovered that the integrated EPR

intensity variations were similar, as shown in Supplementary Fig. 9. This indicates that the EPR signals of Sc3C2@C80 entrapped within porous materials mainly depend on the gas amounts

around the spin probe. Therefore, this nano spin sensor is suitable for probing and evaluating the gas adsorption performance of porous materials. Further, EPR signal linewidths were

analyzed for the nano spin sensor involving Sc3C2@C80 entrapped in Py-COF to reveal the probing mechanism. Notably, compared with the 22 hyperfine coupling splitting peaks of Sc3C2@C80 in a

solution, the free rotation of Sc3C2@C80 embedded in Py-COF is restricted owing to strong host–guest interactions, resulting in significant linewidth broadening, as shown in Fig. 1f.

According to Kivelson’s theory54, the linewidth (_ΔH_) of EPR spectra depends on the quantum number (_M_I) and can be expressed as $$\triangle H=\alpha+\beta {M}_{{{{{{\rm{I}}}}}}}+\gamma

{M}_{{{{{{\rm{I}}}}}}}^{2}+\delta {M}_{{{{{{\rm{I}}}}}}}^{4}$$ (4) where the _α_, _β_, _γ_, and _δ_ parameters depend on the rotational correlation time τc47. From Eq. (4), it can be

inferred that the linewidth was enlarged at both the wing parts of the EPR spectra, and at certain times, a high value of _M_I could cause partial disappearance of the side EPR signals55.

Different EPR signal linewidths of Sc3C2@C80⊂Py-COF under vacuum and after adsorbing N2 and C3H6 at 1 bar successively are shown in Fig. 5. After adsorbing N2, Sc3C2@C80⊂Py-COF demonstrated

slightly increased linewidth compared with Sc3C2@C80⊂Py-COF under vacuum conditions, revealing that adsorbed N2 could further restrict the rotation of embedded Sc3C2@C80. Furthermore, after

adsorbing C3H6 successively, Sc3C2@C80⊂Py-COF had a significantly increased linewidth, revealing the severely restricted rotation of embedded Sc3C2@C80 after adsorbing C3H6. Thus, adsorbed

gases in Py-COF can result in a longer rotational correlation time τc and a larger linewidth for the molecular spin probe involving Sc3C2@C80. EPR STUDIES OF METALLOFULLERENE ENTRAPPED

INSIDE MOF-177 To explore the versatility of this metallofullerene-based nano spin sensor, Sc3C2@C80 was employed to probe the gas adsorption performance of an MOF (MOF-177), as shown in

Fig. 6. For this, Sc3C2@C80 was entrapped in MOF-177 using an adsorption method in a toluene solution, yielding a complex of Sc3C2@C80⊂MOF-177. The mass fraction of Sc3C2@C80 in MOF-177 was

calculated to be 3.78%, and the analysis process is presented in Supplementary Note 4 and Supplementary Fig. 14. The MOF-177 and Sc3C2@C80⊂MOF-177 complexes were characterized using SEM,

which revealed that their morphologies were similar (Supplementary Fig. 15). Moreover, TEM element mapping indicated that Sc3C2@C80 molecules were dispersed in the MOF-177 (Supplementary

Fig. 16). Subsequently, EPR measurements were employed to probe the gas adsorption performance of MOF-177 for N2, H2, CO2, CH4, C3H6, and C3H8. The EPR spectra of Sc3C2@C80⊂MOF-177 under

vacuum and after adsorbing the foregoing gases are shown in Supplementary Fig. 16a, and the corresponding integral EPR spectra are depicted in Fig. 6b. After adsorbing these gases, the EPR

signal intensity of Sc3C2@C80⊂MOF-177 decreased compared to that under vacuum conditions. In addition, the difference values between the integrated EPR signal intensity of Sc3C2@C80⊂MOF-177

before and after adsorbing gases are illustrated in Fig. 6c, demonstrating the following increasing order for the difference values of the integrated EPR signal intensity: N2, H2, CH4, CO2,

C3H8, and C3H6. The adsorption capacity of MOF-177 for the same gases was then measured based on adsorption isotherms, as shown in Supplementary Fig. 16b. Notably, MOF-177 presents

increasing adsorption capacity at 1 bar for the gases in the following order: N2, H2, CH4, CO2, C3H8, and C3H6. As shown in Fig. 6d and Supplementary Fig. 17, a corresponding relationship

exists between the measured adsorption amounts of MOF-177 and changed EPR signals of Sc3C2@C80⊂MOF-177 before and after adsorbing different gases at 1 bar. This distinct relationship reveals

that Sc3C2@C80 embedded in MOF-177 can be employed as a nano spin sensor to probe the gas adsorption performance of MOF-177. In addition, differences still persist between the change trends

obtained from the adsorption isotherm and EPR measurements because the EPR measurement using a spin sensor involving Sc3C2@C80 entrapped in MOF-177 is capable of probing gas with in situ

and real-time monitoring. These results demonstrate that Sc3C2@C80 embedded in porous organic frameworks can act as a nano spin sensor to probe the gas adsorption performance and adsorption

process. DISCUSSION Sc3C2@C80 was embedded into the pores of a Py-COF, and its molecular spin was employed to probe the gas adsorption performance of Py-COF for N2, CO, CO2, CH4, C3H6, and

C3H8. When combined with traditional adsorption isotherm measurements, Sc3C2@C80 exhibited considerably decreased EPR signals upon gas adsorption. The adsorbed gases in Py-COF could restrict

the rotation of embedded Sc3C2@C80 and result in a longer rotational correlation time, a larger linewidth, and decreased intensity for the molecular Sc3C2@C80 nanosensor. We investigated

the sensitivity of this spin probe by recording EPR signals after adsorbing N2, CO, CH4, and CO2 at 0.2 bar and 0.6 bar; the difference values for the integrated EPR signal intensities were

significant, revealing the high sensitivity of the spin probe at low pressures. This high sensitivity was further verified by testing CO2, C3H8, and C3H6 at 0.12, 0.03, and 0.04 bar,

respectively, where these gases at lower pressures were similarly detected. Furthermore, the proposed Sc3C2@C80⊂Py-COF spin sensor was used to probe the adsorption and desorption processes

of C3H6, which revealed that Sc3C2@C80⊂Py-COF could be used to detect the leakage of C3H6 gas, an important and hazardous chemical. The versatility of this Sc3C2@C80 spin sensor was explored

by probing the gas adsorption performance of MOF-177 for N2, H2, CO2, CH4, C3H6, and C3H8. These results demonstrated that Sc3C2@C80 embedded in other porous organic frameworks can also act

as a nano spin sensor to probe the gas adsorption performance, gas adsorption and desorption processes, and gas leakage. The changed difference values for the integrated EPR signal areas

(ΔEPR) of Sc3C2@C80 entrapped within porous materials before and after gas adsorption are dependent on the amount of entrapped Sc3C2@C80, as well as the interaction between Sc3C2@C80 and

nanopores. A larger amount of embedded Sc3C2@C80 would result in a larger ΔEPR; however, the interactions between Sc3C2@C80 and nanopores would influence the EPR signal and ΔEPR. Therefore,

a comparative analysis of ΔEPR could be employed for one type of complex. For example, the amount of Sc3C2@C80 in Py-COF is low (mass fraction: 1.5%); hence, the integrated EPR signal area

and ΔEPR are relatively small compared to those of Sc3C2@C80⊂MOF-177, which has a higher amount of Sc3C2@C80 in MOF-177 (mass fraction: 3.78%). In addition, the different interactions

between Sc3C2@C80 and nanopores of Py-COF and MOF-177 would influence the initial EPR signals. Therefore, when the proposed nano spin sensor is employed to probe the gas adsorption

performance, ΔEPR after adsorbing one gas should be compared with the counterpart under vacuum conditions for one type of complex. Notably, the spin sensor involving Sc3C2@C80 embedded in

porous organic frameworks can probe gas adsorption and desorption processes with in situ and real-time monitoring. Traditional adsorption isotherm measurements often indicate the average

porosity of porous organic frameworks. Therefore, differences are often noted between the change trends obtained from adsorption isotherms and EPR measurements. Compared with the adsorption

amounts measured using adsorption isotherms, the EPR signals have more significant difference values for each gas adsorption (Figs. 2a and 6d). The reason for this is that the commonly used

adsorption isotherm method quantifies the gas adsorption of all pores in porous organic frameworks, whereas EPR measurements only reflect gas adsorption near Sc3C2@C80 in the nanoscale

channel of porous organic frameworks. Therefore, the Sc3C2@C80 nano spin sensor embedded in porous organic frameworks can probe gas adsorption with high sensitivity. Another advantage of

this nano spin sensor is that the required amounts of porous organic frameworks are small. In this study, a milligram mass of porous organic frameworks (ca. 1 mg) was required for adsorption

evaluation with this spin sensor of metallofullerene; however, traditional adsorption isotherm measurements often require significantly more sample amounts (ca. 100 mg). The minimal amount

of sample required indicates that this nano spin sensor has promising applications in the field of trace sensing, wherein a small amount of porous material can facilitate numerous gas

adsorption evaluations. This study revealed the significant interaction between the metallofullerene spin and gas molecules in nanospace. Thus, the molecular spins of metallofullerene can be

employed to probe gas adsorption inside the pores of porous organic frameworks based on their quantum characteristics, demonstrating that metallofullerene-based molecular spins are

applicable for quantum sensing applications. METHODS PREPARATION OF SC3C2@C80 Metallofullerene Sc3C2@C80 was synthesized based on the Kräschmer−Huffman arc-discharge method using an

arc-discharge generator. All reagents were obtained commercially and used without further purification unless otherwise specified. The products were extracted from carbon ash via ultrasound

in an ortho-dichlorobenzene (_o_-DCB) solvent. The extracts were separated through multistage high-performance liquid chromatography with a Buckyprep column (20 × 250 mm) and a Buckyprep-M

column (20 × 250 mm) using toluene as the eluent. Sc3C2@C80 was detected using a matrix-assisted laser desorption/ionization time-of-flight mass spectrometer (AXIMA Assurance, Shimadzu).

SOURCE OF POROUS ORGANIC FRAMEWORKS Py-COF was purchased from Chemsoom Co., Ltd. MOF-177 was prepared using a method reported in the literature56. Briefly, Zn(NO3)2·6H2O (1.8 g) and

1,3,5-Tri(4-carboxyphenyl)benzene (H3BTB, 120 mg) were dissolved in N, N-Dimethylformamide (DMF, 36 ml) and sonicated for 1 h. The mixed solution was then sealed in a glass tube and heated

at 85 °C for 3500 min. The products were washed three times with DMF and three times with toluene. PREPARATION OF SC3C2@C80⊂PY-COF AND SC3C2@C80⊂MOF-177 First, Py-COF and MOF-177 samples

with large sizes and high degrees of crystallinity were selected for preparation. Then, Py-COF (2 mg) powder was immersed in the toluene solution containing Sc3C2@C80 (4 × 10−5 mol·L−1) for

one week to ensure that the Sc3C2@C80 molecules completely entered the channels of Py-COF. The resulting brown powder was washed with toluene and vacuum dried at 80 °C for 12 h to obtain the

Sc3C2@C80⊂Py-COF complex. Sc3C2@C80⊂MOF-177 was prepared according to the method above, and related details are described in Supplementary Note 4. XPS MEASUREMENT The XPS analysis of

Sc3C2@C80⊂Py-COF was performed using the VG Scientific ESCALab220i-XL electron spectrometer with 300 W Al Kα radiation. As is typical, the hydrocarbon C1s line at 284.8 eV from adventitious

carbon was used for energy referencing. SEM AND TEM MEASUREMENT The morphologies and microstructures of the samples were observed using a field emission scanning electron microscope

(Regulus8100, HITACHI, Japan) operated at a voltage of 10 kV, along with a TEM (JEM-2100F, JEOL, Japan). Element mapping was characterized on a TEM equipped with Oxford detection. ELECTRON

PARAMAGNETIC RESONANCE SPECTRUM MEASUREMENTS EPR spectra were recorded on an EPR spectrometer (CIQTEK EPR200-Plus) with a continuous-wave X-band frequency (~9.6 GHz). A small quantity of

complex (0.86 mg for Sc3C2@C80⊂Py-COF and 5.0 mg for Sc3C2@C80⊂MOF-177) was placed at the bottom of a quartz tube. The modulating field strength, frequency, and microwave power were 2 G, 100

 kHz, and 2 mW (20 dB), respectively. To probe the gas adsorption of Py-COF using the molecular spin of Sc3C2@C80, the EPR signals of Sc3C2@C80⊂Py-COF were recorded after adsorbing N2, CO,

CO2, CH4, C3H6, and C3H8. Sc3C2@C80⊂Py-COF (0.86 mg) was placed in a quartz tube connected to a vacuum pump and gas bag (at 1 bar). Sc3C2@C80⊂Py-COF in the quartz tube was evacuated for 30 

min to remove air from the pores before recording EPR signals under vacuum. Then, gases were filled into the quartz tube; after adsorbing for 30 min, the EPR signals were collected. The

detailed test procedure is described in Supplementary Note 2. PXRD MEASUREMENTS The solid samples were loaded onto a glass sample holder to record the PXRD spectra on a Rigaku D/max-2500n

diffractometer with Cu Kα radiation (λ  =  1.541 Å) at 40 kV and 200 mA. The scanning range was from 2_θ_ = 2° to 80° with a scan speed of 2° min−1. GAS ADSORPTION ISOTHERM MEASUREMENTS Gas

adsorption isotherms were recorded on a BeiShiDe Instrument volumetric adsorption analyzer. Prior to the measurements, 100 mg samples were degassed for over 300 min at 300 °C, and the

equilibration time was 120 s. Ultra-high purity N2, CO, H2, CO2, CH4, C3H6, and C3H8 were used for measurements. Oil-free vacuum pumps and oil-free pressure regulators were used for

measurements to prevent contamination of the samples during the degassing process and isotherm measurement. A liquid N2 bath was used for the adsorption measurements at 77 K. Before

measurement, the samples were degassed in vacuum at 150 °C for 300 min. To provide high accuracy and precision in determining P/P0, the saturation pressure P0 was measured throughout the N2

analyses using a dedicated saturation pressure transducer, which allowed us to monitor the vapor pressure at each data point. STATISTICAL INFORMATION Statistics were performed either with

OriginPro 2021 software. The bar chart data in Fig. 5 represents the mean ± SD (_n_ = 20). DATA AVAILABILITY The data that support the findings of this study are available in the online

version of this paper and the accompanying Supplementary Information, or available from the corresponding authors on request. Source data are provided with this paper. CHANGE HISTORY * _ 04

SEPTEMBER 2023 A Correction to this paper has been published: https://doi.org/10.1038/s41467-023-41233-6 _ REFERENCES * Malia, B. K., Wu, Y., Martínez-Rincón, J. & Kasevich, M. A.

Distributed quantum sensing with mode-entangled spin-squeezed atomic states. _Nature_ 612, 661–665 (2022). Article  ADS  CAS  PubMed  Google Scholar  * Takeda, K., Noiri, A., Nakajima, T.,

Kobayashi, T. & Tarucha, S. Quantum error correction with silicon spin qubits. _Nature_ 608, 682–686 (2022). Article  ADS  CAS  PubMed  PubMed Central  Google Scholar  * Pelliccione, M.

et al. Scanned probe imaging of nanoscale magnetism at cryogenic temperatures with a single-spin quantum sensor. _Nat. Nanotechnol._ 11, 700–705 (2016). Article  ADS  CAS  PubMed  Google

Scholar  * Broholm, C. et al. Quantum spin liquids. _Science_ 367, eaay0668 (2020). Article  CAS  PubMed  Google Scholar  * Pribiag, V. S. et al. Electrical control of single hole spins in

nanowire quantum dots. _Nat. Nanotechnol._ 8, 170–174 (2013). Article  ADS  CAS  PubMed  Google Scholar  * Perunicic, V. S., Hill, C. D., Hall, L. T. & Hollenberg, L. C. L. A quantum

spin-probe molecular microscope. _Nat. Commun._ 7, 12667 (2016). Article  ADS  CAS  PubMed  PubMed Central  Google Scholar  * Kinschel, D. et al. Femtosecond X-ray emission study of the spin

cross-over dynamics in haem proteins. _Nat. Commun._ 11, 4145 (2020). Article  ADS  CAS  PubMed  PubMed Central  Google Scholar  * Jackson, D. M. et al. Quantum sensing of a coherent single

spin excitation in a nuclear ensemble. _Nat. Phys._ 17, 585–590 (2021). Article  CAS  Google Scholar  * Ruskuc, A., Wu, C. J., Rochman, J., Choi, J. & Faraon, A. Nuclear spin-wave

quantum register for a solid-state qubit. _Nature_ 602, 408–413 (2022). Article  ADS  CAS  PubMed  Google Scholar  * Rugar, D. et al. Proton magnetic resonance imaging using a

nitrogen–vacancy spin sensor. _Nat. Nanotechnol._ 10, 120–124 (2015). Article  ADS  CAS  PubMed  Google Scholar  * Hamlin, J. J. & Zhou, B. B. Extreme diamond-based quantum sensors.

_Science_ 366, 1312–1313 (2019). Article  ADS  CAS  PubMed  Google Scholar  * Mamin, H. J. et al. Nanoscale nuclear magnetic resonance with a nitrogen-vacancy spin sensor. _Science_ 339,

557–560 (2013). Article  ADS  CAS  PubMed  Google Scholar  * Lesik, M. et al. Magnetic measurements on micrometer-sized samples under high pressure using designed NV centers. _Science_ 366,

1359–1362 (2019). Article  ADS  CAS  PubMed  Google Scholar  * Wasielewski, M. R. et al. Exploiting chemistry and molecular systems for quantum information science. _Nat. Rev. Chem._ 4,

490–504 (2020). Article  CAS  PubMed  Google Scholar  * Heinrich, A. J. et al. Quantum-coherent nanoscience. _Nat. Nanotechnol._ 16, 1318–1329 (2021). Article  ADS  CAS  PubMed  Google

Scholar  * Gaita-Ariño, A., Luis, F., Hill, S. & Coronado, E. Molecular spins for quantum computation. _Nat. Chem._ 11, 301–309 (2019). Article  PubMed  Google Scholar  * Liu, F. et al.

Single molecule magnet with an unpaired electron trapped between two lanthanide ions inside a fullerene. _Nat. Commun._ 8, 16098 (2017). Article  ADS  CAS  PubMed  PubMed Central  Google

Scholar  * Wu, B. et al. Molecular magnetic switch for a metallofullerene. _Nat. Commun._ 6, 6468 (2015). Article  ADS  CAS  PubMed  Google Scholar  * Fu, W. et al. Gd2@C79N: isolation,

characterization, and monoadduct formation of a very stable heterofullerene with a magnetic spin state of S = 15/2. _J. Am. Chem. Soc._ 133, 9741–9750 (2011). Article  CAS  PubMed  PubMed

Central  Google Scholar  * Hu, Z. et al. Endohedral metallofullerene as molecular high spin qubit: diverse rabi cycles in Gd2@C79N. _J. Am. Chem. Soc._ 140, 1123–1130 (2018). Article  CAS 

PubMed  Google Scholar  * Feng, Y. et al. Steering metallofullerene electron spin in porous metal-organic framework. _J. Am. Chem. Soc._ 137, 15055–15060 (2015). Article  CAS  PubMed  Google

Scholar  * Liu, Z. et al. Amination of the Gd@C82 endohedral fullerene: tunable substitution effect on quantum coherence behaviors. _Chem. Sci._ 11, 10737–10743 (2020). Article  CAS  PubMed

  PubMed Central  Google Scholar  * Meng, H. B. et al. Covalently bonded two spin centers of paramagnetic metallofullerene dimer. _Nano Res_. 14, 4658–4663 (2021). Article  ADS  CAS  Google

Scholar  * Meng, H. B., Zhao, C., Nie, M. Z., Wang, C. R. & Wang, T. S. Triptycene molecular rotors mounted on metallofullerene Sc3C2@C80 and their spin-rotation couplings. _Nanoscale_

10, 18119–18123 (2018). Article  CAS  PubMed  Google Scholar  * Wang, Z. F., Zhang, S., Chen, Y., Zhang, Z. J. & Ma, S. Q. Covalent organic frameworks for separation applications. _Chem.

Soc. Rev._ 49, 708–735 (2020). Article  CAS  PubMed  Google Scholar  * Knebel, A. & Caro, J. Metal–organic frameworks and covalent organic frameworks as disruptive membrane materials

for energy-efficient gas separation. _Nat. Nanotechnol._ 17, 911–923 (2022). Article  ADS  CAS  PubMed  Google Scholar  * Cadiau, A., Adil, K., Bhatt, P. M., Belmabkhout, Y. & Eddaoudi,

M. A metal-organic framework-based splitter for separating propylene from propane. _Science_ 353, 137–140 (2016). Article  ADS  CAS  PubMed  Google Scholar  * Qian, Q. et al. MOF-based

membranes for gas separations. _Chem. Rev._ 120, 8161–8266 (2020). Article  CAS  PubMed  Google Scholar  * Mao, H. et al. Designing hierarchical nanoporous membranes for highly efficient gas

adsorption and storage. _Sci. Adv._ 6, eabb0694 (2020). Article  ADS  CAS  PubMed  PubMed Central  Google Scholar  * Connolly, B. M. et al. Tuning porosity in macroscopic monolithic

metal-organic frameworks for exceptional natural gas storage. _Nat. Commun._ 10, 2345 (2019). Article  ADS  CAS  PubMed  PubMed Central  Google Scholar  * Kulkarni, R. et al. Real-time

optical and electronic sensing with a β-amino enone linked, triazine-containing 2D covalent organic framework. _Nat. Commun._ 10, 3228 (2019). Article  ADS  PubMed  PubMed Central  Google

Scholar  * Jo, Y. K. et al. Exclusive and ultrasensitive detection of formaldehyde at room temperature using a flexible and monolithic chemiresistive sensor. _Nat. Commun._ 12, 4955 (2021).

Article  ADS  CAS  PubMed  PubMed Central  Google Scholar  * Dolgopolova, E. A., Rice, A. M., Martin, C. R. & Shustova, N. B. Photochemistry and photophysics of MOFs: steps towards

MOF-based sensing enhancements. _Chem. Soc. Rev._ 47, 4710–4728 (2018). Article  CAS  PubMed  Google Scholar  * Lin, Y. et al. Layer-by-layer growth of preferred-oriented MOF thin film on

nanowire array for high-performance chemiresistive sensing. _Angew. Chem. Int. Ed._ 60, 25758–25761 (2021). Article  CAS  Google Scholar  * Deng, W. H. et al. Non-contact real-time detection

of trace nitro-explosives by MOF composites visible-light chemiresistor. _Natl. Sci. Rev._ 9, nwac143 (2022). Article  CAS  PubMed  PubMed Central  Google Scholar  * Zheng, R. et al. The

growth mechanism of a conductive MOF thin film in spray-based layer-by-layer liquid phase epitaxy. _Angew. Chem. Int. Ed._ 61, e202212797 (2022). Article  ADS  CAS  Google Scholar  *

Sullivan, I. et al. Coupling electrochemical CO2 conversion with CO2 capture. _Nat. Catal._ 4, 952–958 (2021). Article  CAS  Google Scholar  * Han, X. et al. Hollow mesoporous atomically

dispersed metal-nitrogen-carbon catalysts with enhanced diffusion for catalysis involving larger molecules. _Nat. Commun._ 13, 2900 (2022). Article  ADS  CAS  PubMed  PubMed Central  Google

Scholar  * Jin, S. How to effectively utilize MOFs for electrocatalysis. _ACS Energy Lett_ 4, 1443–1445 (2019). Article  CAS  Google Scholar  * Meng, H. B., Zhao, C., Nie, M. Z., Wang, C. R.

& Wang, T. S. Changing the hydrophobic MOF pores through encapsulating fullerene C60 and metallofullerene Sc3C2@C80. _J. Phys. Chem. C_ 123, 6265–6269 (2019). Article  CAS  Google

Scholar  * Meng, H. B., Zhao, C., Nie, M. Z., Wang, C. R. & Wang, T. S. Optically controlled molecular metallofullerene magnetism via an azobenzene-functionalized metal-organic

framework. _ACS Appl. Mater. Interfaces_ 10, 32607–32612 (2018). Article  CAS  PubMed  Google Scholar  * Li, Y. et al. De novo design and facile synthesis of 2D covalent organic frameworks:

A two-in-one strategy. _J. Am. Chem. Soc._ 141, 13822–13828 (2019). Article  CAS  PubMed  Google Scholar  * Kumar, K. V., Preuss, K., Titirici, M. M. & Rodríguez-Reinoso, F. Nanoporous

materials for the onboard storage of natural gas. _Chem. Rev._ 117, 1796–1825 (2017). Article  CAS  PubMed  Google Scholar  * Getman, R. B., Bae, Y. S., Wilmer, C. E. & Snurr, R. Q.

Review and analysis of molecular simulations of methane, hydrogen, and acetylene storage in metal–organic frameworks. _Chem. Rev._ 112, 703–723 (2012). Article  CAS  PubMed  Google Scholar 

* Islamoglu, T. et al. Metal–organic frameworks against toxic chemicals. _Chem. Rev._ 120, 8130–8160 (2020). Article  CAS  PubMed  Google Scholar  * Krätschmer, W., Lamb, L. D.,

Fostiropoulos, K. & Huffman, D. R. Solid C60: a new form of carbon. _Nature_ 347, 354–358 (1990). Article  ADS  Google Scholar  * Wilson, R. & Kivelson, D. ESR linewidths in

solution. i. experiments on anisotropic and spin–rotational effects. _J. Phys. Chem_ 44, 154–168 (1966). Article  CAS  Google Scholar  * Schweiger, A & Jeschke, G. _Principles of pulse

electron. paramagnetic resonance_. (Oxford University Press: Oxford, 2001) 209–213. Book  Google Scholar  * Hsu, D., Lin, J. G. & Wu, W. F. Electron spin resonance studies on

La0.7−xDyxSr0.3MnO3. _J. Magn. Magn. Mater_ 304, e427–e429 (2006). Article  ADS  CAS  Google Scholar  * Son, N. T. et al. Electron paramagnetic resonance and theoretical studies of shallow

phosphorous centers in 3C-, 4H-, and 6H-SiC. _Phy. Rev. B_ 73, 075201 (2006). Article  ADS  Google Scholar  * Sing, K. S. W. Reporting physisorption data for gas/solid systems with special

reference to the determination of surface area and porosity. _Pure Appl. Chem_. 57, 603–619 (1984). Article  Google Scholar  * Sheveleva, A. M. et al. Probing gas adsorption in metal–organic

framework ZIF-8 by EPR of embedded nitroxides. _J. Phys. Chem. C_ 121, 19880–19886 (2017). Article  CAS  Google Scholar  * Poryvaev, A. S., Polyukhov, D. M. & Fedin, M. V. Mitigation of

pressure-induced amorphization in metal-organic framework ZIF-8 upon EPR control. _ACS Appl. Mater. Interfaces_ 12, 16655–16661 (2020). Article  CAS  PubMed  Google Scholar  * Inakuma, M.

& Shinohara, H. Temperature-dependent EPR studies on isolated scandium metallofullerenes: Sc@C82(I, II) and Sc@C84. _J. Phys. Chem. B_ 104, 7595–7599 (2000). Article  CAS  Google Scholar

  * Meng, H. B. et al. An implanted paramagnetic metallofullerene probe within a metal-organic framework. _Nanoscale_ 10, 3291–3298 (2018). Article  CAS  PubMed  Google Scholar  * Chae, H.

K. et al. A route to high surface area, porosity and inclusion of large molecules in crystals. _Nature_ 427, 523–527 (2004). Article  ADS  CAS  PubMed  Google Scholar  Download references

ACKNOWLEDGEMENTS This work was supported by the National Natural Science Foundation of China (52022098, 51972309) and the Youth Innovation Promotion Association of Chinese Academy of

Sciences (Y201910). AUTHOR INFORMATION AUTHORS AND AFFILIATIONS * Beijing National Laboratory for Molecular Sciences, Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute

of Chemistry, Chinese Academy of Sciences, Zhongguancun North First Street 2, Beijing, 100190, China Jie Zhang, Linshan Liu, Chaofeng Zheng, Wang Li, Chunru Wang & Taishan Wang *

University of Chinese Academy of Sciences, Beijing, 100049, China Jie Zhang & Chaofeng Zheng Authors * Jie Zhang View author publications You can also search for this author inPubMed 

Google Scholar * Linshan Liu View author publications You can also search for this author inPubMed Google Scholar * Chaofeng Zheng View author publications You can also search for this

author inPubMed Google Scholar * Wang Li View author publications You can also search for this author inPubMed Google Scholar * Chunru Wang View author publications You can also search for

this author inPubMed Google Scholar * Taishan Wang View author publications You can also search for this author inPubMed Google Scholar CONTRIBUTIONS T.W. and C.W. conceived the research and

supervised the project. J.Z., W.L. and C.Z. performed the material preparations and EPR measurements. L.L. performed the DFT calculations. T.W. and J.Z. wrote the paper. All authors

discussed the results and commented on the manuscript. CORRESPONDING AUTHOR Correspondence to Taishan Wang. ETHICS DECLARATIONS COMPETING INTERESTS The authors declare no competing interest.

PEER REVIEW PEER REVIEW INFORMATION _Nature Communications_ thanks Huilin Liu, Yao Chen and the other, anonymous, reviewers for their contribution to the peer review of this work. A peer

review file is available. ADDITIONAL INFORMATION PUBLISHER’S NOTE Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

SUPPLEMENTARY INFORMATION SUPPLEMENTARY INFORMATION PEER REVIEW FILE SOURCE DATA SOURCE DATA RIGHTS AND PERMISSIONS OPEN ACCESS This article is licensed under a Creative Commons Attribution

4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and

the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s

Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not

permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit

http://creativecommons.org/licenses/by/4.0/. Reprints and permissions ABOUT THIS ARTICLE CITE THIS ARTICLE Zhang, J., Liu, L., Zheng, C. _et al._ Embedded nano spin sensor for in situ

probing of gas adsorption inside porous organic frameworks. _Nat Commun_ 14, 4922 (2023). https://doi.org/10.1038/s41467-023-40683-2 Download citation * Received: 11 January 2023 * Accepted:

01 August 2023 * Published: 15 August 2023 * DOI: https://doi.org/10.1038/s41467-023-40683-2 SHARE THIS ARTICLE Anyone you share the following link with will be able to read this content:

Get shareable link Sorry, a shareable link is not currently available for this article. Copy to clipboard Provided by the Springer Nature SharedIt content-sharing initiative